Rapid Joule-heating synthesis of metal/carbon-based electrocatalysts for efficient carbon dioxide reduction
The synthesis process of M-PANI-T.
USA, July 10, 2024 /EINPresswire.com/ -- In comparison with conventional pyrolysis processes, the researchers developed a rapid thermal shock method to achieve a uniform dispersion of metal nanoparticles on carbon supports. This approach effectively prevented nanoparticle aggregation, ensuring the full utilization of active sites. As a result, the electrocatalysts demonstrated exceptional electrocatalytic activity and selectivity for carbon dioxide reduction.
The electrocatalytic reduction of carbon dioxide into high-value chemicals and fuels offers a promising strategy for addressing the global energy crisis and worsening environmental issues. However, the high thermodynamic stability of CO2 molecules, competitive hydrogen evolution reactions, and the complexity of products pose significant challenges. Therefore, the selection and design of electrocatalysts are crucial for improving product selectivity and energy efficiency.
In a study (https://doi.org/10.1016/j.chphma.2024.06.002) published in the KeAi journal ChemPhysMater, a team of researchers from China introduced a novel approach-the rapid Joule-heating synthesis method that ensures the uniform dispersion of metal nanoparticles (NPs) on carbon supports and enhances the electron conductivity of catalysts.
The functional nanoparticles dispersed on conductive carbons offer substantial benefits to improve the efficiency and selectivity of CO2 reduction. The carbon supports facilitate efficient electron and heat transfer, while also dispersing and stabilizing NPs to prevent aggregation. However, during carbonization synthesis, metal nanoparticles often aggregate to reduce their surface energy, leading to a loss of active area and catalytic deactivation.
Through rapid thermal shock treatment, the researchers achieved a uniform dispersion of metal nanoparticles on a carbon substrate (M-PANI-T). The short duration of thermal shock inhibited the migration of metal atoms, and defects on carbons generated by pyrolysis played a crucial role in anchoring metal nanoparticles. By adjusting the treatment time to vary temperatures, the researchers explored the impact on catalytic performance. Electrochemical testing revealed that catalyst performance depends on both the metal active sites and the carbon supports, rather than solely on individual factors.
According to Jintao Zhang, lead investigator of the study, this breakthrough in the field of functional nanoparticles prepared on carbon substrates demonstrates that the Joule-heating shock method has good universality and excellent electrocatalytic activity. This method can be used to prepare various catalysts for carbon-supported metal nanoparticles, significantly reducing time and raw material costs while providing valuable theoretical insights for future catalyst design.
DOI
10.1016/j.chphma.2024.06.002
Original Source URL
https://doi.org/10.1016/j.chphma.2024.06.002
Funding information
This research was financially supported by the National Natural Science Foundation of China (22175108 and 22379086), the Natural Science Foundation of Shandong Province (ZR2020JQ09 and ZR2022ZD27), and the Taishan Scholars Program of Shandong Province (tstp20221105).
Lucy Wang
BioDesign Research
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